4.7 Article

Polynorbornene derived 8-hydroxyquinoline paper strips for ultrasensitive chemical nerve agent surrogate sensing

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CHEMICAL COMMUNICATIONS
卷 50, 期 62, 页码 8511-8513

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03361b

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The detection of nerve agent simulants is achieved by the photoinduced electron transfer (PET) mechanism. A turn-on fluorescence response upon phosphorylation at 8-hydroxyquinoline of norbornene-based triazolyl functionalized 8-hydroxyquinoline (NCHQ) followed by intramolecular rearrangement provides very intense green emission. The detection limit of polymer (PNCHQ) coated paper strips is 25 ppb with instantaneous response.

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