期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 22, 页码 2873-2875出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49488h
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资金
- National Science Foundation of China [21272087, 21002036, 21202053]
- National Basic Research Program of China [2011CB808603]
- Central China Normal University [CCNU13T04060, 2013YBYB54]
A new type of chiral sulfoxide-phosphine ligands have been developed by a rational combination of two privileged scaffolds for Pd-catalyzed asymmetric allylic alkylation reactions. Under optimized conditions, generally high yields (up to 97%) and excellent enantioselectivities (up to >99% ee) were obtained.
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