期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 75, 页码 10975-10978出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04512b
关键词
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资金
- Spanish grants [SAF2010-20822-C02, CTQ2012-31341, Consolider Ingenio 2010 CSD2007-00006]
- Xunta de Galicia [GRC2010/12, GRC2013-041, INCITE09 209084PR, PGIDIT08CSA-047209PR]
- ERDF
- European Research Council [340055]
- COST Action CM1105
- orfeo-cinqa network
- Spanish MCINN
We report a photolabile biselectrophilic Ru(II) complex that can be used for homo- or heterodimerization of cysteine-containing peptides. The resulting dimers can be efficiently disassembled by long-wavelength light. As proof-of-concept, we describe the preparation of homo- and heterodimeric bZIP peptides whose DNA-binding properties can be turned off using visible light.
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