期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 93, 页码 14631-14634出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06697a
关键词
-
资金
- 973 Program [2012CB821701]
- NSFC [91222201, 21173272, 21103233]
By stepwise functionalization of a T-shaped ligand with amide and N-oxide groups, we obtained a MOF with drastically strengthened CO2-framework interactions, induced by a open donor sites (ODSs) effect, resulting in a high heat of adsorption and high CO2/CH4, CO2/CO and CO2/N-2 separation selectivities at room temperature.
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