期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 59, 页码 7941-7944出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01498g
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资金
- Grants-in-Aid for Scientific Research [25109538, 25410073, 25620048] Funding Source: KAKEN
An unprecedented iron complex-catalyzed dehydrogenation of alcohols was achieved using CpFe(CO)(2)Cl with a base or CpFe(CO)(Py)(Ph) as a catalyst without sacrificing the hydrogen acceptors. This reaction effectively (up to TON 67000) converted 2-pyridylmethanol derivatives to the corresponding ketones or aldehydes. The mechanistic study is also discussed.
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