期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 3, 页码 292-294出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46180g
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资金
- National Natural Science Foundation of China [21303183, 21273231, 21233008]
- Hundred Person Project of the Chinese Academy of Sciences
Gold nanoparticles supported on ceria{110} crystal planes were more reactive than on ceria{111} and {100} in the oxidative dehydrogenation of alcohols. Kinetic analysis and a Hammett plot suggest that hydride transfer is involved, and the cationic gold is catalytically active.
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