期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 25, 页码 3347-3349出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49220f
关键词
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资金
- European Research Council [278593_ORGZEO]
- Deutsche Forschungsgemeinschaft (DFG)
Microporous polymer networks based on binaphthyl phosphoric acids are suitable heterogeneous asymmetric organocatalysts. Herein we show that the porous characteristics of such networks can be fine-tuned by co-polymerisation. This enables us to investigate the influence of the surface area and porosity in microporous networks on their catalytic performance. In this case, the activity of the polymers in an asymmetric hydrogenation reaction is increased by the use of polymers with higher surface areas.
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