期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 20, 页码 2592-2594出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47207h
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资金
- ANPCyT
- UBACyT
- CONICET
- CeBEM
- ANII
- CSIC-UdelaR
- NIH
- NSF
- U.S. Department of Energy's Office of Science
Here we report a spectroscopic, electrochemical and computational study of cytochrome c showing that nitration of Tyr74 induces Tyr deprotonation, which is coupled to Met/Lys axial ligand exchange, and results in concomitant gain of peroxidatic activity at physiological pH.
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