期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 7, 页码 689-691出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37352a
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资金
- Research Grants Council of Hong Kong [PolyU5010/11P]
A palladium-catalyzed cascade cross-coupling of acetanilide and toluene for the synthesis of ortho-acylacetanilide is described. Toluene derivatives can act as effective acyl precursors (upon sp(3)-C-H bond oxidation by a Pd/TBHP system) in the oxidative coupling between two C-H bonds. This dehydrogenative Pd-catalyzed ortho-acylation proceeds under mild reaction conditions.
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