期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 61, 页码 6846-6848出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41564c
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资金
- University of Houston
- Norman Hackerman Advanced Research Program
- National Science Foundation [CHE-1151292]
- American Chemical Society Petroleum Research Fund [50390-DNI10]
- Welch Foundation [E-1571, E-1768]
- Camille and Henry Dreyfus Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1151292] Funding Source: National Science Foundation
Three perfluorinated Cu-based metal-organic frameworks (MOFs) were prepared starting from extensively fluorinated biphenyl-based ligands accessed via C-H functionalization. These new materials are highly hydrophobic: with water contact angles of up to 151 +/- 1 degrees, they are among the most water-repellent MOFs ever reported.
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