期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 80, 页码 9164-9166出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44847a
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资金
- Global Frontier R&D Program on Center for Multiscale Energy System
- National Research Foundation under the Ministry of Science, ICT Future, Korea [2012-8-2081]
- U.S. NSF [CHE-1057904]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1057904] Funding Source: National Science Foundation
The palladium-catalyzed oxidative alkynylation of beta-borylated porphyrins allows for concise preparation of push-pull structured ethynylbenzoic acid porphyrin derivatives. The resulting beta-singly- and doubly-substituted porphyrin dyes are regarded as isomeric derivatives of the corresponding meso-substituted reference systems, and were found to give rise to nearly equal power conversion efficiencies when analyzed in DSSCs.
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