4.7 Article

Cs4Mo5P2O22: a first Strandberg-type POM with 1D straight chains of polymerized [Mo5P2O23]6- units and moderate second harmonic generation response

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 3, 页码 306-308

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36354b

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资金

  1. Natural Science Foundation of Xinjiang Uygur Autonomous Region of China [2009211B33]
  2. 973 Program [2012CB626803]
  3. National Natural Science Foundation of China [U1129301, 51172277, 21101168, 11104344]
  4. Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences [KJCX2-EW-H03-03]
  5. Major Program of Xinjiang Uygur Autonomous Region of China [201130111]
  6. High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China [201116143]

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A noncentrosymmetric chiral Strandberg-type polyoxometalate based material, Cs4Mo5P2O22, that contains unusual one dimensional chains constructed from [Mo5P2O23](6-) units has been reported. Cs4Mo5P2O22 shows a moderate SHG response, and is phase-matchable.

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