期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 39, 页码 4421-4423出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36665g
关键词
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资金
- NSFC [21172075, 21222204]
- Innovation Program of SMEC [12ZZ046]
- Fundamental Research Funds for the Central Universities [11043]
We report the first catalytic asymmetric cyanation of N-Boc ketoimines, which enables highly enantioselective synthesis of oxindole based alpha-amino nitriles. An unprecedented tandem aza-Wittig/Strecker reaction is also developed, emerging as a promising strategy for the catalytic asymmetric cyanation of ketoimines formed in situ from achiral ketones.
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