期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 15, 页码 1506-1508出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38900f
关键词
-
资金
- Deutsche Forschungsgemeinschaft (International Research Training Group Munster-Nagoya) [GRK 1143]
- Deutsche Akademische Austauschdienst [Forschungsstipendium A/12/71607]
A base-free, catalytic protocol for the dehydrogenative Si-N coupling of weakly nucleophilic N-H groups of heteroarenes or aryl-substituted amines with equimolar amounts of hydrosilanes is reported. Cooperative Si-H bond activation at a Ru-S bond generates a silicon electrophile that forms a Si-N bond prior to the N-H deprotonation by an intermediate Ru-H complex, only releasing H-2.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据