期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 11, 页码 1055-1057出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35800j
关键词
-
资金
- 973 Program [2012CB821702, 2011CB935902]
- NSFC [20971074, 91122004]
- NSF of Tianjin [10JCZDJC21700]
Two 24-nuclear lanthanide clusters, Gd-24 and Dy-24 were obtained and structurally characterized. Magnetic investigations reveal that Gd-24 exhibits the largest entropy change (-Delta S-m) of 46.12 J kg(-1) K-1 for Delta H = 7 T in all reported molecular clusters, and single-molecule magnet behaviour is observed in Dy-24.
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