期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 34, 页码 3510-3512出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40542g
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资金
- JST (PRESTO)
- JSPS [21245011, 23350018, 23750129]
- Global 30 Program (MEXT)
- Grants-in-Aid for Scientific Research [23350018, 21245011] Funding Source: KAKEN
Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL(-1) in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z,Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E,Z)-isomers in the highest enantiomeric excesses in the gel state.
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