4.7 Article

Novel bisimidazolium pincers as low loading ligands for in situ palladium-catalyzed Suzuki-Miyaura reaction in the ambient atmosphere

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CHEMICAL COMMUNICATIONS
卷 49, 期 11, 页码 1127-1129

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36375e

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  1. NSFC [20902063, 21172159, 21021001]
  2. SRF for ROCS, SEM [20111568-8-2]

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A series of novel triazinonide-bridged bisimidazolium pincers were easily synthesized by quaternization of functionalized N-phenylimidazoles with highly reactive cyanuric chloride under mild conditions. The pincer 3c was proven to be a very efficient ligand for in situ Pd-catalyzed Suzuki-Miyaura reaction with ppm-level catalyst loading.

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