期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 71, 页码 7794-7796出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43616k
关键词
-
资金
- 973 Project from the MOST of China [2009CB825300]
- NSFC [20925207, 21002001]
The first iron-catalyzed formal cross coupling of homobenzylic methyl ethers with alkyl Grignard reagents is realized. The reaction is proposed to proceed through a sequence of dehydroalkoxylation to form the vinyl-intermediate, followed by Fe-catalyzed selective carbometalation to form a benzylic Grignard reagent.
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