期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 81, 页码 9329-9331出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44059a
关键词
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资金
- National Natural Science Foundation of China [91213302, 20932003, 21272102]
- Ministry of Science and Technology of China [2012ZX09504001-003]
- Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT1137]
Highly efficient asymmetric vinylogous 1,6-Michael addition of alpha,beta-unsaturated gamma-butyrolactam to 3-methyl-4-nitro-5-alkenyl-isoxazoles and Michael addition to trichloromethyl ketones by using a chiral quinine-derived squaramide organocatalyst were described, giving products with high diastereo- and enantioselectivities (up to >25 : 1 dr and 96% ee).
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