期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 39, 页码 4358-4360出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35345h
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资金
- MEXT of Japan [24108725, 2410915, 22105007, 22018026]
- Japan Society for Promotion of Science [23350027]
- Grants-in-Aid for Scientific Research [24108725, 23350027, 24109015, 22018026, 23685040, 22105007] Funding Source: KAKEN
Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.
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