4.7 Article

Colorimetric visualization of acid-base equilibria in non-polar solvent

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 61, 页码 6870-6872

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42859a

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  1. World Premier International Research Center Initiative on Materials Nanoarchitectonics from MEXT, Japan
  2. Core Research for Evolutional Science and Technology (CREST) program of JST, Japan
  3. Japan Society for the Promotion of Science (JSPS)

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Visualization of an acid-base equilibrium in a non-polar solvent (dichloromethane), which may be extended to other solvents, is reported. It is based on an oxoporphyrinogen as a multichromic indicator of prevailing acidity in solution and presents up to six distinct hues depending on degree of protonation, tautomeric state or presence of a basic guest.

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