4.7 Article

One-pot galvanic formation of ultrathin-shell Sn/CoOx nanohollows as high performance anode materials in lithium ion batteries

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 53, 页码 5981-5983

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42109k

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资金

  1. (Basic Science Research Program) through the National Research Foundation of Korea [NRF-2012-004029]
  2. MEST
  3. Priority Research Centers Program [NRF-2012-1040282]
  4. WCU program [R31-2008-10029]

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The thermolysis of a heterobimetallic Sn-Co organometallic precursor resulted in the formation of hollow Sn/CoOx nanomaterials through galvanic reaction between metal species. The Sn/CoOx nanohollows with 6.1 nm diameter and similar to 1.5 nm shell thickness showed excellent lithium storage capacity of up to 857 mA h g(-1) after 30 cycles.

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