4.7 Article

Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?

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CHEMICAL COMMUNICATIONS
卷 49, 期 45, 页码 5234-5236

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41184b

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  1. Korean Research Council

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Dodecaborates, i.e. the [B12H12](2-) containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)(3), yttrium octahydrotriborate, i.e. Y(B3H8)(3), rather than the stable Y-2(B12H12)(3), is formed as the main intermediate.

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