4.7 Article

Iodine-templated assembly of unprecedented 3d-4f metal-organic frameworks as photocatalysts for hydrogen generation

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 34, 页码 3564-3566

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc39173f

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资金

  1. NNSF of China [21001022, 21171033, 21131001, 21222105]
  2. Program for New Century Excellent Talents in Chinese University [NCET-10-0282]
  3. PhD Station Foundation of Ministry of Education [20100043110003]
  4. Foundation for Author of National Excellent Doctoral Dissertation of P.R. China (FANEDD) [201022]
  5. Science and Technology Development Planning of Jilin Province [201001169, 20111803]

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Unprecedented 3d-4f MOFs encapsulating infinite linear polyiodide chains were firstly reported using iodine molecules as a versatile precursor template. They possess high framework stability in acid/base aqueous solutions. The kinetics of iodine molecule release/recovery and UV-light photocatalytic H-2 evolution activities were investigated.

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