期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 100, 页码 11728-11730出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46597g
关键词
-
资金
- 973 Project'' [2012CB821706]
- NSFC [21001120, 21121061, 21225105]
By virtue of planar Cu-2(mu-OH)(2)(2+) cluster units, a flexible porous metal azolate framework not only adsorbs large amounts of CO2 (19.6 wt% or 266 g L-1 at 298 K and 1 atm) with a high zero-coverage adsorption enthalpy (-47 kJ mol(-1)), but also desorbs quickly at very low temperatures.
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