期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 89, 页码 10516-10518出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45986a
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资金
- University of South Florida
- NSF [CHE-0844602]
- U.S. Department of Energy through BES Grant [DE-FG02-08ER46522]
- Direct For Mathematical & Physical Scien [0844602] Funding Source: National Science Foundation
- Division Of Chemistry [0844602] Funding Source: National Science Foundation
A strategy for building highly connected robust MOFs from linear ligands is exemplified by the construction of MTAF-4, a rare (6,9)-connected MOF, based on the custom-designed bifunctional linear ligand, 4-(1,2,3-triazol-4-yl)-benzoate, that connects two types of highly connected zinc cluster moieties generated in situ. MTAF-4 is robust and permanently microporous and is capable of adsorbing CO2, H-2 and CH4 under high pressures.
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