4.7 Article

Molybdate templated assembly of Ln(12)Mo(4)-type clusters (Ln = Sm, Eu, Gd) containing a truncated tetrahedron core

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CHEMICAL COMMUNICATIONS
卷 49, 期 1, 页码 36-38

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36530h

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  1. 973 Project from MSTC [2012CB821704]
  2. NNSFC [20825103, 90922031, 21021061]

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Three heterometallic cluster complexes {Ln(12)Mo(4)} featuring an Ln(12) core of a distorted truncated tetrahedron were synthesized with the assistance of four MoO42- anions as ancillary ligands. Magnetic studies of the {Gd12Mo4} cluster revealed a large magnetocaloric effect due to the presence of the large number of weakly coupled Gd(III) ions.

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