期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 76, 页码 8534-8536出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45126g
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资金
- EPSRC
- MBase
- Actinet-I3
- Engineering and Physical Sciences Research Council [1091989] Funding Source: researchfish
Effects of bromine substitution at the 5 and 5,6-positions of the 1,10-phenanthroline nucleus of BTPhen ligand on their extraction properties for Ln(III) and An(III) cations have been studied. Compared to C5-BTPhen, electronic modulation in BrC5-BTPhen and Br(2)C5-BTPhen enabled these ligands to be fine-tuned in order to enhance the separation selectivity of Am(III) from Eu(III).
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