期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 61, 页码 6912-6914出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42423e
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The catalyst system prepared in situ from iron(III) salts, tris(2-pyridylmethyl)amine and a base readily catalyses the intradiol dioxygenation of pyrocatechol in methanol, to primarily afford the half-methyl ester of muconic acid. Dimethyl adipate is obtained by the subsequent, one-step catalytic hydrogenation/esterification, thus providing a green route to this important nylon precursor.
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