期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 52, 页码 5853-5855出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42307g
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资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21025206, 21272180]
- China Postdoctoral Science Foundation [2012M521458]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp(3)-H bonds was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic studies showed that the Csp(3)-H metallation step was a slow step.
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