期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 45, 页码 5186-5188出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41466c
关键词
-
资金
- Natural Science Foundation of China [21171012]
This article describes the photo-induced living radical polymerization of acrylamides mediated by organo-cobalt porphyrins through photo-cleavage of the Co-C bond to give organic radicals, which propagate polymerization, and cobalt(II), which is a persistent metal-centered radical. Photo stimulus controls the initiation steps and regulates chain growth by activating the Co-C bond.
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