期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 39, 页码 4292-4294出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35762c
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An unusual cleavage of the non-ylidic carbon-sulfur bond of a sulfonium ylide is reported. The reaction can be catalysed by a variety of palladium(II) complexes under mild conditions. Preliminary results show that coordination of the ylide to the metal center results in significant structural changes.
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