期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 26, 页码 2709-2711出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38546a
关键词
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资金
- NSFC of China [20973064, 20925310, U1162102]
- MOST of China [2012BAE05B02]
- STCSM [12JC1403600]
- Shanghai Municipal Education Commission [13zz038]
- Shanghai Leading Academic Discipline Project [B409]
A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)(3) species, this novel core-shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.
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