期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 70, 页码 7714-7716出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42594k
关键词
-
资金
- Swiss government fellowship for excellence
- Swiss National Science Foundation
OvoA is an iron(II) dependent sulfoxide synthase which catalyzes the first step in ovothiol A biosynthesis. This enzyme sulphurizes the C-5 position of the imidazole side chain of L-histidine. We report the substrate specificity profile of this catalyst and present data which indicate that OvoA catalysis follows an thiol-ene type mechanism.
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