期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 39, 页码 4316-4318出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37137e
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Grants-in-Aid for Scientific Research [23550167] Funding Source: KAKEN
A novel mixed-valence Cu(I)-Cu(II) coordination polymer with an infinite two-dimensional structure, [(Cu3CuBr3)-Cu-I-Br-II(3,5-Dmpip-dtc)(2)](n) (3,5-Dmpip-dtc(-) = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.
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