期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 56, 页码 6343-6345出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42506a
关键词
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资金
- National Natural Science Foundation of China [21272155, 21272147]
- Innovation Program of Shanghai Municipal Education Commission [13YZ010]
- Beijing National Laboratory for Molecular Sciences
The complexation behavior of pillar[6] arene hosts towards a carbonium ion, tropylium tetrafluoroborate (T center dot BF4), and the formation of novel charge-transfer (CT) inclusion complexes are described. In contrast, smaller pillar[5]arenes and larger pillar[7]arenes cannot form such complexes due to the unsuitable cavity dimensions.
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