4.7 Article

Chemically crosslinked isoreticular metal-organic frameworks

期刊

CHEMICAL COMMUNICATIONS
卷 49, 期 31, 页码 3200-3202

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40635k

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资金

  1. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-FG02-08ER46519]
  2. National Science Foundation Graduate Research Fellowship [DGE1144086]
  3. The Hellman Fellowship Program (UCSD)

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Herein we report the synthesis of canonical isoreticular metal-organic frameworks (IRMOFs) containing interligand crosslinks. Chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH2-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.

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