期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 25, 页码 2500-2502出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38727e
关键词
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资金
- MEXT, Japan [20108010]
- NRF/MEST of Korea through CRI
- GRL [2010-00353]
- WCU [R31-2008-000-10010-0]
- Global COE program of Osaka University
- Grants-in-Aid for Scientific Research [20108010] Funding Source: KAKEN
Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(IV)-oxo complex.
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