期刊
CHEMICAL COMMUNICATIONS
卷 49, 期 29, 页码 2956-2973出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc39053e
关键词
-
资金
- U.S. Department of Energy, Office of Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division [DE-FG02-09ER16067]
- Direct For Mathematical & Physical Scien [1040541] Funding Source: National Science Foundation
- Division Of Chemistry [1040541] Funding Source: National Science Foundation
In the last few years, considerable progress has been made in the synthesis and characterization of complexes containing actinide-ligand multiple bonds, especially in regards to isolation of terminal oxo, nitrido and carbene-containing complexes. This review summarizes the synthesis, structure, and reactivity of these complexes, from 2010 until present. These complexes are of interest for a variety of reasons, including their potential use in novel catalytic transformations and their ability to engage the 5f orbitals in metal-ligand bonding. Of particular note are the recent syntheses of the first isolable complex containing the nitride-substituted uranyl ion, [NUO](+), and the first report of an isolable terminal uranium nitride. Considerable progress has also been made toward the syntheses of actinide carbenes and thorium complexes containing metal-ligand multiple bonds.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据