期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 62, 页码 7708-7710出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33304j
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资金
- Fonds der Chemischen Industrie (Liebig fellowship)
- Deutsche Forschungsgemeinschaft (DFG)
- Ministerio Espanol de Economia y Competitividad
Unexpected trends in the strengths of halogen-bond based adducts of CY3I (Y = F, Cl, Br, I) with two typical Lewis bases (chloride and trimethylamine) show that the halogen-bond donor strength (Lewis acidity) of a compound R-X is not necessarily increased with higher electronegativity of the (carbon-based) group R.
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