期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 86, 页码 10627-10629出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35754b
关键词
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资金
- NSFC [21102013, 20803030]
- Dalian Committee of Science and Technology [2011J21DW001]
- SRF for ROCS-SEM [201001438, 201001439]
- Fundamental Funds for the Central Universities [DUT11LK20]
- RFDP [20090041120017]
Two novel D-pi-A-pi-D structured small molecules composed of benzothiadiazole and triphenylamine were designed and synthesized. BDCTBT with cyano on the pi-bridge exhibited a deep HOMO energy level, resulting in an impressive V-OC of up to 1.04 V with a PCE of 3.85%, while non-cyano substituted BDETBT yielded a V-OC of 0.94 V and a PCE of 1.99%.
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