期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 14, 页码 2021-2023出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc15931g
关键词
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资金
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology (MEST) [2011-0018595]
Palladium nanoparticles (PdNPs) were conveniently prepared in tetraglyme (TG) solution using a variety of palladium precursors. At 140 degrees C, TG promoted Pd-3(OAc)(6) to produce irregular shaped PdNPs with an average size of 4 nm. When these PdNPs were re-dispersed in TG and used for the dehydrogenation of ammonia borane (AB) at 85 degrees C, remarkably enhanced catalytic performance was achieved to release 2.3 equiv. of H-2 in 1 h.
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