期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 63, 页码 7805-7807出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33773h
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资金
- ERC
- EPSRC
- Engineering and Physical Sciences Research Council [EP/G004528/2] Funding Source: researchfish
- EPSRC [EP/G004528/2] Funding Source: UKRI
We report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decrease in thermal stability upon amorphization is also evident.
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