期刊
HOLZFORSCHUNG
卷 54, 期 6, 页码 604-608出版社
WALTER DE GRUYTER & CO
DOI: 10.1515/HF.2000.102
关键词
DHP; MWL; quantitative C-13 NMR; C-13-enrichment
The possibility that preformed dehydrogenation polymer (DHP) could function as a template to induce a structural pattern in DHP more closely resembling that of natural softwood lignin was investigated by oxidizing beta C-13-labelled coniferyl alcohol in a medium containing preformed unlabelled polymeric DHP. The experiments were performed at pH 4 and pH 6.5. 1D and 2D NMR were used to estimate the distribution of structural units. No such template effect was found in a comparison of unlabelled with uniformly labelled DHP. Indeed, the effect of pH on the coupling pattern of coniferyl alcohol was geater than the effect of the preformed DHP.
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