期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 6, 页码 883-885出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc16261f
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资金
- U.S. Department of Energy (DOE) [DE-SC0001015, DE-FC36-07GO17033, DE-AR0000073]
- National Science Foundation (NSF) [CBET-0930079]
- Welch Foundation [A-1725]
- Spanish Government [CTQ2006/03949BQU]
- Ramon y Cajal contract
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [0930079] Funding Source: National Science Foundation
A metal-organic framework (MOF) with helical channels has been constructed by bridging helical chain secondary building units with 2,6-di-p-carboxyphenyl-4,4'-bipyridine ligands. The activated MOF shows permanent porosity and gas adsorption selectivity. Remarkably, the MOF exhibits a facile transition from micro- to meso-porosity.
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