期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 47, 页码 5850-5852出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31689g
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资金
- City University of Hong Kong [9380047]
Several intermediates and different reaction paths were identified for the acid catalysed conversion of fructose to 5-( hydroxymethyl)-2- furaldehyde (HMF) in different solvents. The structural information combined with results of isotopic-labelling experiments allowed the determination of the irreversibility of the three steps from the fructofuranosyl oxocarbenium ion to HMF as well as the analogous pyranose route.
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