期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 82, 页码 10198-10200出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36091h
关键词
-
资金
- National Science Foundation of China [21172129, 20928005]
- Ministry of Science and Technology of China [2011DFA30620]
N-Phosphorylation labeling was utilized to analyze small metabolites using matrix-assisted laser desorption-ionization time-of-flight mass spectrometry (MALDI-TOF MS). The incorporation of a neutral phosphoryl group with high gas-phase proton affinity not only improved the ionization efficiency of the target molecules, but also greatly reduced the matrix background interference.
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