期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 32, 页码 3806-3808出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18032d
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre in Green Chemistry and Catalysis (CGCC)
- Canada Foundation for Innovation
- Universite Laval
A highly enantioselective method for the catalytic opening of aromatic meso-epoxides with aniline derivatives was developed. The desired chiral beta-amino alcohols were obtained in mostly good to very good yields with excellent enantioselectivities. Structural evidence of the pre-catalyst revealed a scarcely disclosed heptadentate Fe(II) complex with the chiral bipyridine ligand.
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