期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 78, 页码 9732-9734出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34967a
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资金
- U.S. Department of Energy, Office of Science, Early Career Research Program [DE-AC52-06NA25396]
Complexation of Pu(IV) with TMDGA, TEDGA, and TODGA diglycolamide ligands was followed by vis-NIR spectroscopy. A crystal structure determination reveals that TMDGA forms a 1 : 3 homoleptic Pu(IV) complex with the nitrate anions forced into the outer coordination sphere.
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