期刊
CHEMICAL COMMUNICATIONS
卷 48, 期 84, 页码 10440-10442出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35415b
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资金
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1048367] Funding Source: National Science Foundation
A copper(I) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric analysis (TGA), solution based H-1 NMR studies and surface chemistry to determine its thermal stability and decomposition mechanism. Copper(I) tert-butyl-imino-2,2-dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible decomposition in TGA experiments up to 300 degrees C as well as no decomposition in solutions at 165 degrees C over 3 weeks.
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